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Tag: oxygen

Why Do I Need To Change My Oil?

January 24, 2022Written by Charleen

What Happens to oil Making Me Needing to Change It?

Dan McClelland|Jan 07, 2020 8:36 AM

Regardless of its quality, every motor oil eventually loses its potency and must be changed to ensure peak engine protection. Let’s take a look at what happens to motor oil over time and why you periodically need to change oil.

Losing the base

Base oils are the backbone of the finished lubricant that ends up in your engine. Over time, they lose effectiveness due to the following factors:

Oxidation

The interaction between oxygen molecules and motor oil molecules naturally leads to chemical breakdown.

Just as oxygen causes a cut apple to brown or exposed metal to rust, it breaks down base oils and reduces motor oil’s effectiveness.

Oxidation can lead to increased oil viscosity, which negatively affects energy efficiency. It also causes the formation of harmful deposits and sludge.

High heat

Today’s engines run hotter than ever before, with temperatures up to 235°F (113ºC), and even higher if towing or hauling.

The rate of oxidation for oil doubles for every 18°F (10°C) increase in temperature.

Moisture

Your vehicle is subjected to temperature swings, even when it is parked in the garage.

Those temperature swings cause condensation to form inside your engine, leading to water contamination.

Leaving a vehicle parked for extended periods or taking short trips that don’t allow the engine to fully warm up allow water to remain in the oil rather than evaporating and exiting through the tailpipe. Water can lead to formation of sludge…yet another reason why you must change oil.

Viscosity is a motor oil’s most important property. The lower the viscosity, the faster the oils flows, like water. Thicker oils flow more slowly, like honey.

Viscosity loss

A lubricant’s viscosity is its most important property.

Viscosity has a direct bearing on wear protection, and your engine is designed to operate best using a motor oil of a specific viscosity (e.g. 5W-30).

The intense pressure the oil bears as it’s squeezed between moving parts, like the piston ring/cylinder wall interface, can tear apart, or shear, its molecular structure, leading to viscosity loss.

Suddenly, the 5W-30 motor oil your engine was designed to use is now essentially a 5W-20 oil, and wear protection may be compromised. When this happens, it’s time to change your oil.

Shop AMSOIL Synthetic Motor Oil

Fuel dilution

Fuel can wash past the piston rings and contaminate the motor oil, causing it to lose viscosity.

Frequent short trips that don’t allow the oil to reach normal operating temperature can be especially problematic because the fuel won’t volatilize and exit through the PCV system.

Excessive fuel dilution leads to sludge and varnish, requiring you to change oil more frequently.

Additives: Additives are added to base oils to reduce destructive processes and enhance beneficial properties.

For example, antioxidant additives help slow the rate of oxidation. Detergency additives help prevent deposits and sludge while cleaning pre-existing deposits. Formulators add anti-wear additives to some lubricants to form a sacrificial barrier on metal components and help prevent wear.

Since they’re sacrificial in nature, additive depletion is one of the primary reasons motor oil loses its effectiveness and must be changed.

While AMSOIL synthetic motor oil gives you the convenience of fitting oil changes into your schedule, it remains vital to install fresh oil at the appropriate time.

Shop AMSOIL XL 12,000 mile Synthetic Motor Oil

Knowledge Base additive depletion, change oil, engine, fresh oil, high heat, lose viscosity, maintenance, moisture, oxidation, oxygen, rust, sludge, tailpipe

A closer Look At Engine Sludge

June 22, 2020Written by Charleen

Preventing Causes of Engine Oil SLUDGE

Brands matter, quality matters and frequent oil changes will not alter this. It’s all based on the additive quality and it does effect the price.

Engine sludge occurs when oxidized oil and contaminants build up on engine surfaces. It can restrict the flow of oil to the point of engine failure and costly repairs.

As the oil installed in your vehicle ages, oxygen reacts with the lubricant, resulting in a permanent chemical change. The oil picks up oxygen and becomes thicker. Just like oxygen attacks metal surfaces and causes corrosion, it negatively affects lubricants and reduces their ability to lubricate, cool and protect components. Excessive heat speeds the oxidation process. In fact, every 18°F (10°C) increase in temperature doubles the rate of oxidation.

Adding to the challenge, contaminants begin to form during normal operation. In engines, hot combustion gases can blow by the piston rings and contaminate engine oil. Glycol from engine coolant, water that forms with temperature fluctuations and fuel are other common contaminants that affect lubricants. Left unchecked, contaminants accelerate chemical reactions, which overload the lubricant and cause the formation of sludge – a gelatinous substance that wreaks havoc in engines.

Sludge can block the oil passages and oil-pump pick-up screen, resulting in oil starvation. Often, the negative effects are cumulative rather than sudden. Many engines with variable valve timing (VVT) use oil pressure-operated mechanical devices to change valve timing, duration and lift. Sludge can plug the solenoid screen or oil gallies and impact the operation of VVT mechanisms, eventually leading to a costly repair bill. Sludge reduces efficiency and increases time and money spent on maintenance.

Signature Series vs. Sludge

Signature Series Synthetic Motor Oil was subjected to the Sequence VG test to measure its ability to prevent sludge. As expected, Signature Series produced an oil pick-up tube screen virtually free from sludge (see image below). Our unique combination of detergents and high-quality base oils control oxidation and sludge to keep engines clean and efficient.

AMSOIL synthetic lubricants not only resist oxidation and sludge formation, they can help clean existing deposits in neglected engines due to superior detergency. With modern engines and equipment demanding higher-quality lubricants, it’s good to know AMSOIL synthetic lubricants are formulated to protect against sludge in the toughest operating conditions.

Sludge: a gelatinous substance that wreaks havoc in engines.

Signature Series has 50 percent more
detergents¹ to help keep oil passages clean and promote oil circulation. It provides 90% better protection against sludge².

Synthetic Warehouse note:

We own an ecoboost engine (on our Ford van) so based on our personal experience the Signature Series is the only choice in these engines. They run extremely hot effecting the process mentioned above. Test the oil you are using now at or near Ford’s maximum interval and I’m certain it’s beyond it’s life!! TBN and Oxidation levels can be at dangerous levels. Signature Series gives you that extra benefit of the doubt because when the detergents dissipate you can start to have severe wear from corrosion and of course needless deposits from sludge AND increased oil consumption. We eliminated 75% of a resent F150 Ecoboost V6 oil consumption problem using the Engine Flush (FLSH) and the Signature Series 5W-30 (ASL).

It’s not just about keeping your car or truck longer. It’s the issues our competition causes such as carbon coating your intake valves which is an issue on modern gasoline direct injection engines. It’s very costly to clean these as there is no-longer the gasoline we enjoyed as the cleaning agent. Fuel is shot directly into the quench area so oil vapors land on valves and build up over time.
Some newer cars do have an additional injector in the throttle body for start-up and cleaning but this will not be the common setup.

So AMSOIL Signature series will keep these areas cleaner as that’s part of what you are paying for. AMSOIL’s lowest volatility is by far worth paying for. And in some cases you pay less for our product than several of the “so called synthetics”.

Make our Sioux Falls locations your only source for lubricants! Many have made the switch for good. We’re at 47073 98th St just behind Marlins Diner. Exit 73 on I29. Or call to make sure I’m there at 605-274-2580.

Maintenance amsoil, asl, corrosion, detergents, ecoboost, engine sludge, ford, oil starvation, oxidation, oxygen, signature series, sioux falls, VVT

Small engine won’t start? Identifying the Cause.

June 22, 2020Written by Charleen

Small engine won’t start?

Bad gas is the number-one reason, and here’s how to prevent it.

Len Groom | TECHNICAL PRODUCT MANAGER, POWERSPORTS

In northern Minnesota, where I live, the temperature occasionally breaks 80ºF (27ºC) in the summer. When it does, it’s time to fire up my Jet-Skis* and hit the lake. The last thing I want to do on a sunny summer day is mess around with equipment that refuses to start or run properly.

Bad gasoline is the number-one reason seasonal equipment starts hard or runs rough. Over time, gasoline changes, leaving behind gums, varnish and other solids that foul the fuel system and prevent gas from flowing into the combustion chamber. In severe cases, gasoline can change so dramatically that it no longer ignites.

Gasoline is predominantly a mixture of carbon and hydrogen atoms bonded together into energy-dense hydrocarbons. Like conventional base oils, it’s derived from crude oil via a distillation process that uses heat, pressure and other catalysts to create different fractions. Gasoline is comprised of hydrocarbons that are lighter than those found in, for example, diesel fuel or conventional base oils. Refiners add ethanol to the formulation, typically 10 percent, but as high as 85 percent.

Time Takes Its Toll – You Must Treat Gasoline

Time, however, takes its toll on gasoline. Exposure to heat, humidity, atmospheric pressure, oxygen and other variables degrade fuel.

In addition to gums and varnish becoming more concentrated and less soluble as lighter hydrocarbons evaporate, gas is continually oxidizing, which further contributes to varnish and other gunk. Gasoline oxidizes more quickly than motor oil and its negative effects are more immediately noticeable. That’s why it’s important to use high quality gas and store it in approved containers where air infiltration is limited, like inside a ventilated garage or shed, and not in the back of your truck or under the deck.

Meanwhile, ethanol added to gasoline at the refinery can absorb water from the atmosphere, which can lead to phase separation, which occurs when ethanol and gas separate, much like oil and water. Ethanol that has absorbed enough moisture and has sat long enough can foul the fuel system and prevent the engine from starting.

AMSOIL Fights Corrosion

AMSOIL provides corrosion protection Sea Foam® Motor Treatment can’t match, helping maintain power and performance and keeping metal looking like new even when subjected to salt water. ?

? Based upon independent testing of AMSOIL Gasoline
Stabilizer obtained Nov. 8, 2018 and Sea Foam Motor
Treatment purchased Oct. 25, 2018 in a modified NACE
TM0172 using synthetic sea water per ASTM D665 part B.

This all sounds dire, but it’s nothing treating your gasoline with AMSOIL Gasoline Stabilizer (AST) can’t solve. Gasoline Stabilizer keeps fuel fresh up to 12 months. AMSOIL Quickshot® (AQS) stabilizes gasoline during short-term storage up to six months, in addition to providing potent cleaning benefits and protection against ethanol issues.

What does stabilizer do?

That explanation may suit some people, but this is Tech Talk, so let’s look at the chemistry behind gasoline stabilizers.

You’ve probably heard terms like “free radicals” and “antioxidants” in relation to your health. A free radical is an unpaired electron, and most are unstable and highly reactive. They can either donate an electron to, or accept an electron from, other molecules. This starts a chain reaction that can lead to oxidative stress and cell damage. Left unchecked, free radicals can lead to health problems, like cardiovascular disease and cancer. To help fight free radicals, we should eat plenty of foods rich in antioxidants, which lessen their effects. Antioxidants can “donate” an electron to free radicals or trap them, effectively reducing their instability without becoming unstable themselves. Antioxidants aren’t silver bullets, but they go a long way toward improving our health.

By analogy, gasoline stabilizer is an antioxidant for your gasoline. It disrupts the free-radical-induced chain reaction that causes gas to oxidize and form varnish and gums. Some stabilizer products, like Quickshot, also contain chemistry that increases solvency and breaks down existing varnish, helping clean a dirty carburetor and restore performance. As shown, Gasoline Stabilizer also fights corrosion better than Sea Foam Motor Treatment.

Neglecting to stabilize your gas can lead to all sorts of headaches when it’s time to remove your lawnmower, generator, string trimmer or Jet-Ski from storage. For best results, stabilize your gasoline all year long. That’ll ensure your equipment is ready to roll when you are.