The Dynamics of Engine Oil Oxidation

John Baker | Aug 7, 2024 10:59 AM

You guessed it, the key ingredient to engine oxidation is oxygen.

Oxygen comprises about 20 percent of our atmosphere. It’s the third most common element in the universe. Without it we’d all be doomed.

And yet too much of it can cause problems inside your engine.

What is oxidation?

Oxidation occurs when the addition of oxygen changes a chemical substance. Take an apple, for example. Everyone knows that oxygen will quickly cause a cut apple to turn brown. Or metal. Oxygen can cause rust to form on some metals in a matter of days. Have you ever noticed your brakes grinding after having left your car sit for a couple days in wet weather? That sound is your brake pads scouring rust from the rotors. Never worry about that one as driving soon burns that off..

More wear on or in your engine occurs during storage. The oxidation discussed below can be detrimental. And that is not limited to the motor oil but the coolant system as well.

Motor oil isn’t immune to oxidation. As oil reacts with oxygen, a permanent chemical change occurs that causes oil molecules to lose one or more electrons. This can result in several problems, including…

Formation of sludge and deposits that reduce engine efficiency and increase the risk of engine failure
Increased oil viscosity, which reduces fuel efficiency
Additive depletion, reducing the oil’s effectiveness
Accelerated degradation, causing you to change oil more often

Heat accelerates oxidation

Every 18ºF (10ºC) increase in temperature doubles the rate of oxidation. That doesn’t bode well for motorists driving modern turbocharged vehicles that create increased heat compared to older vehicles. Or that Harley waiting in lines of traffic at events when block temps exceed 400F.

Heat isn’t the only oxidation accelerant – certain metals, acids and water can also hasten oxidation. So can large volumes of entrained air, known as foaming.

Can we prevent motor oil oxidation?

Unfortunately, no. Nature is a relentless force, and all motor oil will eventually oxidize to some degree. But we can dramatically slow oxidation through use of synthetic base oils and quality oxidation-inhibitor additives.

AMSOIL synthetic lubricants are formulated using base oils with a saturated molecular structure, meaning oxygen is prevented from attaching. This provides inherent heat and oxidation stability compared to unsaturated conventional oils.

And, because AMSOIL synthetic lubricants don’t contain contaminants like conventional oils, their base composition doesn’t accelerate oxidation.

AMSOIL synthetic lubricants also contain high-quality oxidation inhibitors. These additives are sacrificial in nature, meaning they’re designed to deplete over time. Because AMSOIL synthetic lubricants have inherently better oxidation resistance, their oxidation inhibitors last longer since they don’t deplete as rapidly.

When components and additives are selected for blending, cost is never a deciding factor thus our formulations will always result in the best of class. As AMSOIL does not have stock holders there are no outsiders to effect our decisions to always use the very best.

So, what does that mean to me?

That all adds up to a motor oil that…

Lasts longer despite intense heat and stress
Helps keep your engine cleaner and more efficient
Saves money in the long run through reduced maintenance
And as a bonus you enjoy added performance

So, while oxygen lets you breathe, AMSOIL synthetic motor oil lets you breath easy since your engine is protected against oxidation.

What Happens to oil Making Me Needing to Change It?

Dan McClelland|Jan 07, 2020 8:36 AM

Regardless of its quality, every motor oil eventually loses its potency and must be changed to ensure peak engine protection. Let’s take a look at what happens to motor oil over time and why you periodically need to change oil.

Losing the base

Base oils are the backbone of the finished lubricant that ends up in your engine. Over time, they lose effectiveness due to the following factors:

Oxidation

The interaction between oxygen molecules and motor oil molecules naturally leads to chemical breakdown.

Just as oxygen causes a cut apple to brown or exposed metal to rust, it breaks down base oils and reduces motor oil’s effectiveness.

Oxidation can lead to increased oil viscosity, which negatively affects energy efficiency. It also causes the formation of harmful deposits and sludge.

High heat

Today’s engines run hotter than ever before, with temperatures up to 235°F (113ºC), and even higher if towing or hauling.

The rate of oxidation for oil doubles for every 18°F (10°C) increase in temperature.

Moisture

Your vehicle is subjected to temperature swings, even when it is parked in the garage.

Those temperature swings cause condensation to form inside your engine, leading to water contamination.

Leaving a vehicle parked for extended periods or taking short trips that don’t allow the engine to fully warm up allow water to remain in the oil rather than evaporating and exiting through the tailpipe. Water can lead to formation of sludge…yet another reason why you must change oil.

Viscosity is a motor oil’s most important property. The lower the viscosity, the faster the oils flows, like water. Thicker oils flow more slowly, like honey.

Viscosity loss

A lubricant’s viscosity is its most important property.

Viscosity has a direct bearing on wear protection, and your engine is designed to operate best using a motor oil of a specific viscosity (e.g. 5W-30).

The intense pressure the oil bears as it’s squeezed between moving parts, like the piston ring/cylinder wall interface, can tear apart, or shear, its molecular structure, leading to viscosity loss.

Suddenly, the 5W-30 motor oil your engine was designed to use is now essentially a 5W-20 oil, and wear protection may be compromised. When this happens, it’s time to change your oil.

Shop AMSOIL Synthetic Motor Oil

Fuel dilution

Fuel can wash past the piston rings and contaminate the motor oil, causing it to lose viscosity.

Frequent short trips that don’t allow the oil to reach normal operating temperature can be especially problematic because the fuel won’t volatilize and exit through the PCV system.

Excessive fuel dilution leads to sludge and varnish, requiring you to change oil more frequently.

Additives: Additives are added to base oils to reduce destructive processes and enhance beneficial properties.

For example, antioxidant additives help slow the rate of oxidation. Detergency additives help prevent deposits and sludge while cleaning pre-existing deposits. Formulators add anti-wear additives to some lubricants to form a sacrificial barrier on metal components and help prevent wear.

Since they’re sacrificial in nature, additive depletion is one of the primary reasons motor oil loses its effectiveness and must be changed.

While AMSOIL synthetic motor oil gives you the convenience of fitting oil changes into your schedule, it remains vital to install fresh oil at the appropriate time.

Shop AMSOIL XL 12,000 mile Synthetic Motor Oil

Tag: oxidation

What Causes Engine Oil Oxidation?