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How Engine Sludge Forms. And How To Prevent It.

How Engine Sludge Forms. And How To Prevent It.

It’s ugly. It’s sludge.

Sludge.

It’s a disgusting phenomenon. Even the word sounds gross, like the thing it’s describing. The word for this is onomatopoeia, a strange word that many of us learned in high school English class. Splash. Grunt. Whoosh. Swish. Hiss. Frumpy. You know what I’m talking about.

What is sludge?

Sludge is a black gelatinous goo that renders equipment inoperable if not dealt with. And long before the engine’s demise, sludge can foul its sensors and interfere with performance. Some mechanics call it the “black death.”

How does motor oil, which is fluid, become a semi-solid paste or gel inside an engine?

How engine sludge forms

Essentially the formation of engine sludge is the result of a series of chemical reactions. The lubricant itself degrades as it is exposed to oxygen and elevated temperatures. The higher the temperature, the more rapid the rate of degradation. The by-products of this reaction form highly reactive compounds that further degrade the lubricant. Their by-products then react with other contaminants, forming organic acids and high-molecular-weight polymeric products. These products further react, forming the insoluble product known more commonly as sludge. What begins as a thin film of lacquer or varnish deposits on hot or cold metal surfaces eventually bakes into an expensive mess.

Synthetic base oils help prevent sludge

Fortunately, sludge and varnish deposits are something we oil manufacturers have a measure of control over. Using thermally stable base oils reduces the rate of initial degradation (oxidation). A good example of this is the use of common synthetic base oils such as API Group III, PAOs and Esters. Anti-oxidant additives help reduce the rate of degradation as well. One of the most widely used is zinc dithiophosphate. Not only is it an excellent oxidation inhibitor, it is an outstanding anti-wear additive as well.

So do high-quality additives

We can further address many of the issues occurring after the initial oxidation stage. Additive chemistry such as detergents and dispersants are commonly part of motor oil formulation. They help promote the suspension of contaminants within the oil and keep them from agglomerating. Detergents, which are also alkaline in nature, assist in neutralizing acids that are generated in the sludge-building process. Anti-oxidant, dispersant and detergent additives are consumed during use. To achieve maximum life expectancy, use an oil with high concentrations of these additives.

Severe service invites sludge

Good lubricants minimize sludge and varnish issues. How the equipment is used also has a bearing on the likelihood of sludge or varnish issues.

Stop-and-go driving, frequent/long-term idling and operation in excessively hot or cold weather can all increase the likelihood of sludge and varnish, especially if using more volatile conventional oils.

Interestingly, most auto manufactures note in their owner’s manual that operation under any of the above conditions is considered severe service and requires more frequent oil changes. From a mechanical standpoint, things like adding too much oil to the oil sump, antifreeze contamination, excessive soot loading, excessive oil foaming, poor engine combustion efficiency, excessive blow-by and emission-control-system issues can all lead to the formation of sludge and varnish.

By practicing good maintenance and using properly formulated, premium synthetic lubricants, like AMSOIL synthetic motor oil, your vehicle won’t succumb to the “black death.”

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Why Motor Oil Deteriorates

Why Motor Oil Deteriorates

 

Like just about everything else, motor oil has a lifespan. Even the best oils eventually require you to change them. Historically, many motorists like the convenience of changing oil with the seasons, visiting the quick lube or pulling the ramps out of their garage each spring and fall.

Motor oil can deteriorate by becoming contaminated, the additives depleting over time or both.

How oil becomes contaminated

Base oils are the backbone of the finished lubricant that ends up in your engine. They can be conventional, synthetic or a combination thereof. They’re responsible for lubricating components, which reduces friction and protects against wear.

Base oils can lose their effectiveness over time due to a few different factors.

Oxidation – The interaction between oxygen molecules and motor oil molecules naturally leads to chemical breakdown. Just as oxygen causes a cut apple to brown or exposed metal to rust, it breaks down base oils and reduces motor oil’s effectiveness. Oxidation can lead to increased oil viscosity, which negatively affects energy efficiency. It also causes the formation of harmful deposits and sludge.

High heat – Today’s engines run hotter than ever before, with temperatures up to 235°F, and even higher if towing or hauling. The rate of oxidation for oil doubles for every 18°F increase in temperature.

Moisture – Your vehicle is also subjected to temperature swings, even when it is parked in the garage. Those temperature swings cause condensation to form inside your engine, leading to water contamination. Leaving a vehicle parked for extended periods or taking short trips that don’t allow the engine to fully warm up allow water to remain in the oil rather than evaporating and exiting through the tailpipe. Water can lead to formation of sludge.

Viscosity loss – A lubricant’s viscosity is its most important property. Viscosity has a direct bearing on wear protection, and your engine is designed to operate best using a motor oil of a specific viscosity (e.g. 5W-30). The intense pressure the oil bears as it’s squeezed between moving parts, like the piston ring/cylinder wall interface, can tear apart, or shear, its molecular structure, leading to viscosity loss. Suddenly, the 5W-30 motor oil your engine was designed to use is now essentially a 5W-20 oil, and wear protection may be compromised.

Fuel dilution – Fuel can wash past the piston rings and contaminate the motor oil, causing it to lose viscosity. Frequent short trips that don’t allow the oil to reach normal operating temperature can be especially problematic because the fuel won’t volatilize and exit through the PCV system. Excessive fuel dilution leads to sludge and varnish, requiring the oil to be changed more often.

Additive are designed to deplete

Additives are added to base oils to reduce destructive processes and enhance beneficial properties. For example, antioxidant additives help slow the rate of oxidation. Detergency additives help prevent deposits and sludge while cleaning pre-existing deposits. Anti-wear additives are added to some lubricants to form a sacrificial barrier on metal components and help prevent wear.

Since they’re sacrificial in nature, additive depletion is one of the primary reasons motor oil loses its effectiveness and must be changed.

Though all motor oils eventually deteriorate, synthetic oils last longer than conventional oils and deliver improved protection against wear and deposits. They’re formulated with base oils that are more resilient to oxidation and heat, while their additives also typically offer improved performance.

In fact, AMSOIL Signature Series Synthetic Motor Oil performs so well you can go up to 25,000 miles/one year between oil changes (15,000 miles/one year in severe service) if you want, saving money.